Home ยป Past Questions ยป Chemistry ยป Jamb ยป 1991 ยป Page 2
22

NO(g) + CO(g) โ†” (1)/(2)N2(g) + CO2(g) โˆ†H = 89.3 kj.
What conditions would favour maximum conversion of nitrogen (II) oxide and carbon (II) oxide in the reaction above?

  • A. Low temperature and high pressure
  • B. High temperature and low pressure
  • C. High temperature and high pressure
  • D. Low temperature and low pressure
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23

1.1 g of CaCI2 dissolved in 50 cm3 of water caused a rise in temperature of 3.4ยฐC. The heat of reaction, โˆ†H for CaCI2 in kj per mole is?

(Ca = 40, CI = 35.5, specific heat of water is 4.18 jk-1)

  • A. -71.1
  • B. -4.18
  • C. +71.1
  • D. +111.0
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24

Magnesium (IV) oxide is known to hasten the decomposition of hydrogen peroxide. Its main action is to?

  • A. increase the surface area of the reactants
  • B. increase the concntration of the reactants
  • C. lower the activation energy for the reaction
  • D. lower the heat of reaction, โˆ†H, for the reaction
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25

2H2S(g) + SO2(g) โ†’ 3S(s) + 2H2O(I). The above reaction is?

  • A. a redox reaction H2S is the oxidant and SO2 is the reductant
  • B. a redox reaction in which SO2 is the oxidant and H2S is the reductant
  • C. not a redox reaction because there is no oxidant in reaction equation
  • D. not a redox because there is no reductant in the reaction equation
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26

MnO4 + 8H+ + ne โ†’ Mn++ + 4H2O. Which is the value of n in the reaction above?

  • A. 2
  • B. 3
  • C. 4
  • D. 5
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27

Which of the following equimolar solutions, Na2CO3 Na2 SO
4CI FeCI3 CH3COONa,
have pH greater than 7?

  • A. FeCI 3 and NH 4CI
  • B. Na2CO3, CH3COONa and Na,Na2SO4
  • C. Na2CO3 and CH3COONa
  • D. FeCI3, CH3COONa and NH4CI
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28

If a current of 1.5 A is passed for 4.00 hours through a molten tin salt and 13.3g of tin is deposited, what is the oxidation state of the metal in the salt?

(Sn = 118.7, F = 96500 C mol-1)

  • A. 1
  • B. 2
  • C. 3
  • D. 4
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29

What volume of CO2 at s.t.p would be obtained by reacting trioxocarbonate (IV) with excess acid?

(G.M.V at s.t.p = 22.4 dm3)

  • A. 2.240 cm 3
  • B. 22.40 cm 3
  • C. 224.0 cm 3
  • D. 2240 cm 3
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30

How many structural isomers can be written for the alkyl bromide, C4H9Br?

  • A. 3
  • B. 4
  • C. 6
  • D. 8
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31

50 cm\(^3\) of sulphur (IV) oxide, 800cm\(^3\) of ammonia, 450 cm\(^3\) of hydrogen chloride, 1.0 cm\(^3\)of Carbon(IV) oxide will respectively saturate 1.0 cm\(^3\) of water at 15ยฐC. Which of the following is suitable for demonstrating the fountain experiment?

  • A. Sulphur (IV) oxide and hydrogen chloride
  • B. Carbon (IV) oxide and ammonia
  • C. Ammonia and hydrogen chloride
  • D. Carbon (IV) oxide and surphur (IV) oxide
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32

A property of a colloidal dispersion which a solution does not have is?

  • A. the Tyndall effect
  • B. homogeneity
  • C. osmotic pressure
  • D. surface polarity
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33

A sample of temporary hard water can be prepared in the laboratory by?

  • A. disolving calcium chloride in distilled water
  • B. saturating lime water with carbon (IV) oxide
  • C. saturating distilled water with calcium hydroxide
  • D. dissolving sodium hydrogen trioxocarbonate (IV) in some distilled water
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34

The solubility of copper (II) tetraoxosulphate (Iv) is 75g in 100g of water at 100ยฐC and 25g in 100g of water at 30ยฐC. What mass of the salt would crystallize, if 50g of copper (II) tetraoxosulphate (VI) solution saturated at 100ยฐC were cooled to 30ยฐC ?

  • A. 57.5
  • B. 42.2
  • C. 28.6
  • D. 14.3
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35

Which of the following ions is a pollutant in drinking water even in trace amounts?

  • A. Ca2+
  • B. Hg2+
  • C. Mg2+
  • D. Fe2+
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36

A quantity of air was passed through a weighed amount of alkaline pyrogallol. An increase in the weight of the pyrogallol would result from the absorption of?

  • A. nitrogen
  • B. neon
  • C. argon
  • D. oxygen
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37

Which of the following is arranged in order of increasing electronegativity?

  • A. Chlorine, aluminium, magnesium, phosphorus, sodium
  • B. sodium, magnesium, aluminium, phosphorus, chlorine
  • C. Chlorine, phosphorus, phosphorous, aluminium, magnesium, sodium
  • D. Sodium, chlorine, phosphorus, magnesium, aluminium
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38

Which of the following represents the type of bonding present in ammonium chloride molecule?

  • A. Ionic only
  • B. Covalent only
  • C. Ionic and dative covalent
  • D. Dative covalent only
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39

The ions X and Y+ are isoelectronic, each containing a total of 10 electrons.
How many protons are in the nuclei of the neutral atoms of X and Y respectively?

  • A. 10 and 10
  • B. 9 and 9
  • C. 11 and 9
  • D. 9 and 11
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40

The electronic configuration of an elements is 1s22s22p63s23p3. How many unpaired electrons are there in the element?

  • A. 5
  • B. 4
  • C. 3
  • D. 2
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41

Atoms of element X (with 2 electrons in the outer shell). combine with atoms of Y (with 7 electrons in the outer shell). Which of the following statements is FALSE? The compound formed?

  • A. has formula XY
  • B. is likely to be ionic
  • C. contains X2+ ions
  • D. contains Y- ions
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42

A sample of a gas exerts a pressure of 8.2 atm when confined in a 2.93 dm3 container at 20ยฐC. The number of moles of gas in the sample is?

(R = 0.082 litre atm / deg mole)

  • A. 1.00
  • B. 2.00
  • C. 3.00
  • D. 4.00
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