Chemistry JAMB, WAEC, NECO AND NABTEB Official Past Questions

22

NO(g) + CO(g) ↔ (1)/(2)N2(g) + CO2(g) ∆H = 89.3 kj.
What conditions would favour maximum conversion of nitrogen (II) oxide and carbon (II) oxide in the reaction above?

  • A. Low temperature and high pressure
  • B. High temperature and low pressure
  • C. High temperature and high pressure
  • D. Low temperature and low pressure
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23

1.1 g of CaCI2 dissolved in 50 cm3 of water caused a rise in temperature of 3.4°C. The heat of reaction, ∆H for CaCI2 in kj per mole is?

(Ca = 40, CI = 35.5, specific heat of water is 4.18 jk-1)

  • A. -71.1
  • B. -4.18
  • C. +71.1
  • D. +111.0
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24

Magnesium (IV) oxide is known to hasten the decomposition of hydrogen peroxide. Its main action is to?

  • A. increase the surface area of the reactants
  • B. increase the concntration of the reactants
  • C. lower the activation energy for the reaction
  • D. lower the heat of reaction, ∆H, for the reaction
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25

2H2S(g) + SO2(g) → 3S(s) + 2H2O(I). The above reaction is?

  • A. a redox reaction H2S is the oxidant and SO2 is the reductant
  • B. a redox reaction in which SO2 is the oxidant and H2S is the reductant
  • C. not a redox reaction because there is no oxidant in reaction equation
  • D. not a redox because there is no reductant in the reaction equation
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26

MnO4 + 8H+ + ne → Mn++ + 4H2O. Which is the value of n in the reaction above?

  • A. 2
  • B. 3
  • C. 4
  • D. 5
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27

Which of the following equimolar solutions, Na2CO3 Na2 SO
4CI FeCI3 CH3COONa,
have pH greater than 7?

  • A. FeCI 3 and NH 4CI
  • B. Na2CO3, CH3COONa and Na,Na2SO4
  • C. Na2CO3 and CH3COONa
  • D. FeCI3, CH3COONa and NH4CI
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28

If a current of 1.5 A is passed for 4.00 hours through a molten tin salt and 13.3g of tin is deposited, what is the oxidation state of the metal in the salt?

(Sn = 118.7, F = 96500 C mol-1)

  • A. 1
  • B. 2
  • C. 3
  • D. 4
View Answer & Discuss JAMB 1991
29

What volume of CO2 at s.t.p would be obtained by reacting trioxocarbonate (IV) with excess acid?

(G.M.V at s.t.p = 22.4 dm3)

  • A. 2.240 cm 3
  • B. 22.40 cm 3
  • C. 224.0 cm 3
  • D. 2240 cm 3
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30

How many structural isomers can be written for the alkyl bromide, C4H9Br?

  • A. 3
  • B. 4
  • C. 6
  • D. 8
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31

50 cm\(^3\) of sulphur (IV) oxide, 800cm\(^3\) of ammonia, 450 cm\(^3\) of hydrogen chloride, 1.0 cm\(^3\)of Carbon(IV) oxide will respectively saturate 1.0 cm\(^3\) of water at 15°C. Which of the following is suitable for demonstrating the fountain experiment?

  • A. Sulphur (IV) oxide and hydrogen chloride
  • B. Carbon (IV) oxide and ammonia
  • C. Ammonia and hydrogen chloride
  • D. Carbon (IV) oxide and surphur (IV) oxide
View Answer & Discuss JAMB 1991
32

A property of a colloidal dispersion which a solution does not have is?

  • A. the Tyndall effect
  • B. homogeneity
  • C. osmotic pressure
  • D. surface polarity
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33

A sample of temporary hard water can be prepared in the laboratory by?

  • A. disolving calcium chloride in distilled water
  • B. saturating lime water with carbon (IV) oxide
  • C. saturating distilled water with calcium hydroxide
  • D. dissolving sodium hydrogen trioxocarbonate (IV) in some distilled water
View Answer & Discuss JAMB 1991
34

The solubility of copper (II) tetraoxosulphate (Iv) is 75g in 100g of water at 100°C and 25g in 100g of water at 30°C. What mass of the salt would crystallize, if 50g of copper (II) tetraoxosulphate (VI) solution saturated at 100°C were cooled to 30°C ?

  • A. 57.5
  • B. 42.2
  • C. 28.6
  • D. 14.3
View Answer & Discuss JAMB 1991
35

Which of the following ions is a pollutant in drinking water even in trace amounts?

  • A. Ca2+
  • B. Hg2+
  • C. Mg2+
  • D. Fe2+
View Answer & Discuss JAMB 1991
36

A quantity of air was passed through a weighed amount of alkaline pyrogallol. An increase in the weight of the pyrogallol would result from the absorption of?

  • A. nitrogen
  • B. neon
  • C. argon
  • D. oxygen
View Answer & Discuss JAMB 1991
37

Which of the following is arranged in order of increasing electronegativity?

  • A. Chlorine, aluminium, magnesium, phosphorus, sodium
  • B. sodium, magnesium, aluminium, phosphorus, chlorine
  • C. Chlorine, phosphorus, phosphorous, aluminium, magnesium, sodium
  • D. Sodium, chlorine, phosphorus, magnesium, aluminium
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38

Which of the following represents the type of bonding present in ammonium chloride molecule?

  • A. Ionic only
  • B. Covalent only
  • C. Ionic and dative covalent
  • D. Dative covalent only
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39

The ions X and Y+ are isoelectronic, each containing a total of 10 electrons.
How many protons are in the nuclei of the neutral atoms of X and Y respectively?

  • A. 10 and 10
  • B. 9 and 9
  • C. 11 and 9
  • D. 9 and 11
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40

The electronic configuration of an elements is 1s22s22p63s23p3. How many unpaired electrons are there in the element?

  • A. 5
  • B. 4
  • C. 3
  • D. 2
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41

Atoms of element X (with 2 electrons in the outer shell). combine with atoms of Y (with 7 electrons in the outer shell). Which of the following statements is FALSE? The compound formed?

  • A. has formula XY
  • B. is likely to be ionic
  • C. contains X2+ ions
  • D. contains Y- ions
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42

A sample of a gas exerts a pressure of 8.2 atm when confined in a 2.93 dm3 container at 20°C. The number of moles of gas in the sample is?

(R = 0.082 litre atm / deg mole)

  • A. 1.00
  • B. 2.00
  • C. 3.00
  • D. 4.00
View Answer & Discuss JAMB 1991