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Alkylation of benzene is catalyzed by

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Chemistry JAMB 2024

Alkylation of benzene is catalyzed by 

  • palladium
  • nickel
  • sunlight
  • aluminium chloride checkmark

The correct answer is: D

Explanation

Alkylation is the process of substituting an alkyl group into a benzene ring, replacing a hydrogen on the ring with a group like methyl or ethyl. 

Alkylation of benzene can be catalyzed by a number of substances, including:

  • Aluminum chloride: A common catalyst for the Friedel-Crafts alkylation of benzene. Aluminum chloride acts as a Lewis acid, coordinating with halogens to generate an electrophile. 
  • Fluorinated alumina: Catalyzes the alkylation of benzene with propylene. 
  • Methyl- and ethylsilanes: Catalyze the alkylation of benzene with ethylene and propylene. 
  • Acidic zeolite catalysts: Such as mordenite, which can be used to alkylate benzene with 1-dodecene. 
  • Boron trifluoride: Catalyzes the alkylation of benzene with 2-propanol, forming a carbocation intermediate that attaches to the benzene ring

There is an explanation video available .

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